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Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA
Environmental Chemistry and Ecotoxicology, Volume: 7, Pages: 275 - 285
Swansea University Author: Guangling Zhao
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DOI (Published version): 10.1016/j.enceco.2025.01.005
Abstract
Copper anode slime (CAS) is a byproduct produced during copper electrorefining process. It contains metals such as gold, silver, copper, selenium, tellurium etc. Without proper treatment, CAS posed significant environmental hazard due to its toxic components. Recovering critical metals from CAS not...
| Published in: | Environmental Chemistry and Ecotoxicology |
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| ISSN: | 2590-1826 |
| Published: |
Elsevier BV
2025
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa68710 |
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<?xml version="1.0"?><rfc1807><datestamp>2025-01-20T11:49:08.2238889</datestamp><bib-version>v2</bib-version><id>68710</id><entry>2025-01-20</entry><title>Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA</title><swanseaauthors><author><sid>20da587f584c918135bfb383eaaec62c</sid><firstname>Guangling</firstname><surname>Zhao</surname><name>Guangling Zhao</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2025-01-20</date><deptcode>EAAS</deptcode><abstract>Copper anode slime (CAS) is a byproduct produced during copper electrorefining process. It contains metals such as gold, silver, copper, selenium, tellurium etc. Without proper treatment, CAS posed significant environmental hazard due to its toxic components. Recovering critical metals from CAS not only mitigates environmental risks but also serves as an important source of these valuable materials. Recycling of critical metals can significantly enhance metal recycling efficiency and support the advancement of a circular economy. However, this process could introduce potential environmental impacts due to the increased consumption of energy, chemical material, and water. The process requires comprehensive assessment. In this study, life cycle assessment is employed to evaluate the potential environmental impact of the four resource recovery processes for copper anode slime: pyrometallurgy, hydrometallurgy, semi-hydrometallurgy, and combining bio-hydrometallurgy and semi-hydrometallurgy (CBS). The functional unit is 1 kg of copper anode slime. 5 metals are recycled during the process named: cupper (Cu), tellurium (Te), selenium (Se), gold (Au), and silver (Ag). Six impact categories—climate change, freshwater ecotoxicity, marine ecotoxicity, terrestrial ecotoxicity, human toxicity (cancer), and human toxicity (non-cancer)—were assessed and compared across the four recycling technologies. The LCA results show that CBS has the lowest environmental impact among all the assessed impact categories. CBS process demonstrated superior metal recovery rates. Hydrometallurgy has the lowest energy and material costs. CBS incurs higher total costs due to the use of expensive chemicals like potassium iodide.</abstract><type>Journal Article</type><journal>Environmental Chemistry and Ecotoxicology</journal><volume>7</volume><journalNumber/><paginationStart>275</paginationStart><paginationEnd>285</paginationEnd><publisher>Elsevier BV</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>2590-1826</issnPrint><issnElectronic/><keywords>Copper anode slime; Life cycle assessment; Critical metal recovery technology; Cost analysis</keywords><publishedDay>16</publishedDay><publishedMonth>1</publishedMonth><publishedYear>2025</publishedYear><publishedDate>2025-01-16</publishedDate><doi>10.1016/j.enceco.2025.01.005</doi><url/><notes/><college>COLLEGE NANME</college><department>Engineering and Applied Sciences School</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EAAS</DepartmentCode><institution>Swansea University</institution><apcterm>External research funder(s) paid the OA fee (includes OA grants disbursed by the Library)</apcterm><funders>UKRI (EP/W019167/1)</funders><projectreference/><lastEdited>2025-01-20T11:49:08.2238889</lastEdited><Created>2025-01-20T11:36:34.1756431</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Materials Science and Engineering</level></path><authors><author><firstname>Yu</firstname><surname>Li</surname><order>1</order></author><author><firstname>Jenny</firstname><surname>Baker</surname><order>2</order></author><author><firstname>Yaxi</firstname><surname>Fang</surname><order>3</order></author><author><firstname>Haizhou</firstname><surname>Cao</surname><order>4</order></author><author><firstname>Cameron</firstname><surname>Pleydell-Pearce</surname><order>5</order></author><author><firstname>Trystan</firstname><surname>Watson</surname><order>6</order></author><author><firstname>Sha</firstname><surname>Chen</surname><order>7</order></author><author><firstname>Guangling</firstname><surname>Zhao</surname><order>8</order></author></authors><documents><document><filename>68710__33373__9650bebd67f94755919cb5f783084fe6.pdf</filename><originalFilename>68710.VoR.pdf</originalFilename><uploaded>2025-01-20T11:41:35.7917403</uploaded><type>Output</type><contentLength>1029062</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><documentNotes>© 2024 The Authors. This is an open access article under the CC BY license.</documentNotes><copyrightCorrect>true</copyrightCorrect><language>eng</language><licence>http://creativecommons.org/licenses/by/4.0/</licence></document></documents><OutputDurs/></rfc1807> |
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2025-01-20T11:49:08.2238889 v2 68710 2025-01-20 Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA 20da587f584c918135bfb383eaaec62c Guangling Zhao Guangling Zhao true false 2025-01-20 EAAS Copper anode slime (CAS) is a byproduct produced during copper electrorefining process. It contains metals such as gold, silver, copper, selenium, tellurium etc. Without proper treatment, CAS posed significant environmental hazard due to its toxic components. Recovering critical metals from CAS not only mitigates environmental risks but also serves as an important source of these valuable materials. Recycling of critical metals can significantly enhance metal recycling efficiency and support the advancement of a circular economy. However, this process could introduce potential environmental impacts due to the increased consumption of energy, chemical material, and water. The process requires comprehensive assessment. In this study, life cycle assessment is employed to evaluate the potential environmental impact of the four resource recovery processes for copper anode slime: pyrometallurgy, hydrometallurgy, semi-hydrometallurgy, and combining bio-hydrometallurgy and semi-hydrometallurgy (CBS). The functional unit is 1 kg of copper anode slime. 5 metals are recycled during the process named: cupper (Cu), tellurium (Te), selenium (Se), gold (Au), and silver (Ag). Six impact categories—climate change, freshwater ecotoxicity, marine ecotoxicity, terrestrial ecotoxicity, human toxicity (cancer), and human toxicity (non-cancer)—were assessed and compared across the four recycling technologies. The LCA results show that CBS has the lowest environmental impact among all the assessed impact categories. CBS process demonstrated superior metal recovery rates. Hydrometallurgy has the lowest energy and material costs. CBS incurs higher total costs due to the use of expensive chemicals like potassium iodide. Journal Article Environmental Chemistry and Ecotoxicology 7 275 285 Elsevier BV 2590-1826 Copper anode slime; Life cycle assessment; Critical metal recovery technology; Cost analysis 16 1 2025 2025-01-16 10.1016/j.enceco.2025.01.005 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University External research funder(s) paid the OA fee (includes OA grants disbursed by the Library) UKRI (EP/W019167/1) 2025-01-20T11:49:08.2238889 2025-01-20T11:36:34.1756431 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Yu Li 1 Jenny Baker 2 Yaxi Fang 3 Haizhou Cao 4 Cameron Pleydell-Pearce 5 Trystan Watson 6 Sha Chen 7 Guangling Zhao 8 68710__33373__9650bebd67f94755919cb5f783084fe6.pdf 68710.VoR.pdf 2025-01-20T11:41:35.7917403 Output 1029062 application/pdf Version of Record true © 2024 The Authors. This is an open access article under the CC BY license. true eng http://creativecommons.org/licenses/by/4.0/ |
| title |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
| spellingShingle |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA Guangling Zhao |
| title_short |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
| title_full |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
| title_fullStr |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
| title_full_unstemmed |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
| title_sort |
Comparative environmental impacts analysis of technologies for recovering critical metals from copper anode slime: Insights from LCA |
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20da587f584c918135bfb383eaaec62c |
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20da587f584c918135bfb383eaaec62c_***_Guangling Zhao |
| author |
Guangling Zhao |
| author2 |
Yu Li Jenny Baker Yaxi Fang Haizhou Cao Cameron Pleydell-Pearce Trystan Watson Sha Chen Guangling Zhao |
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Journal article |
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Environmental Chemistry and Ecotoxicology |
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7 |
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275 |
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2025 |
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Swansea University |
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2590-1826 |
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10.1016/j.enceco.2025.01.005 |
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Elsevier BV |
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Faculty of Science and Engineering |
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School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering |
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| description |
Copper anode slime (CAS) is a byproduct produced during copper electrorefining process. It contains metals such as gold, silver, copper, selenium, tellurium etc. Without proper treatment, CAS posed significant environmental hazard due to its toxic components. Recovering critical metals from CAS not only mitigates environmental risks but also serves as an important source of these valuable materials. Recycling of critical metals can significantly enhance metal recycling efficiency and support the advancement of a circular economy. However, this process could introduce potential environmental impacts due to the increased consumption of energy, chemical material, and water. The process requires comprehensive assessment. In this study, life cycle assessment is employed to evaluate the potential environmental impact of the four resource recovery processes for copper anode slime: pyrometallurgy, hydrometallurgy, semi-hydrometallurgy, and combining bio-hydrometallurgy and semi-hydrometallurgy (CBS). The functional unit is 1 kg of copper anode slime. 5 metals are recycled during the process named: cupper (Cu), tellurium (Te), selenium (Se), gold (Au), and silver (Ag). Six impact categories—climate change, freshwater ecotoxicity, marine ecotoxicity, terrestrial ecotoxicity, human toxicity (cancer), and human toxicity (non-cancer)—were assessed and compared across the four recycling technologies. The LCA results show that CBS has the lowest environmental impact among all the assessed impact categories. CBS process demonstrated superior metal recovery rates. Hydrometallurgy has the lowest energy and material costs. CBS incurs higher total costs due to the use of expensive chemicals like potassium iodide. |
| published_date |
2025-01-16T07:30:40Z |
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1850743183906963456 |
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11.08895 |

