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A Fullerene–Platinum Complex for Direct Functional Patterning of Single Metal Atom-Embedded Carbon Nanostructures

Dongxu Yang, Xiangyi Chen, Dongsheng He Orcid Logo, Andreas Frommhold, Xiaoqing Shi, Stuart A. Boden, Maria A. Lebedeva Orcid Logo, Olga V. Ershova, Richard Palmer Orcid Logo, Ziyou Li, Haofei Shi, Jianzhi Gao, Minghu Pan Orcid Logo, Andrei N. Khlobystov Orcid Logo, Thomas W. Chamberlain Orcid Logo, Alex P. G. Robinson

The Journal of Physical Chemistry Letters, Volume: 13, Issue: 6, Pages: 1578 - 1586

Swansea University Author: Richard Palmer Orcid Logo

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Abstract

The development of patterning materials (“resists”) at the nanoscale involves two distinct trends: one is toward high sensitivity and resolution for miniaturization, the other aims at functionalization of the resists to realize bottomup construction of distinct nanoarchitectures. Patterning of carbo...

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Published in: The Journal of Physical Chemistry Letters
ISSN: 1948-7185 1948-7185
Published: American Chemical Society (ACS) 2022
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa60488
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Abstract: The development of patterning materials (“resists”) at the nanoscale involves two distinct trends: one is toward high sensitivity and resolution for miniaturization, the other aims at functionalization of the resists to realize bottomup construction of distinct nanoarchitectures. Patterning of carbon nanostructures, a seemingly ideal application for organic functional resists, has been highly relianton complicated pattern transfer processes because of a lack of patternable precursors. Herein, we present a fullerene−metal coordination complex as a fabrication material for direct functional patterning of sub-10 nm metal-containing carbon structures. The attachment of one platinum atom per fullerene molecule not only leads to significant improvement of sensitivity and resolution but also enables stable atomic dispersion of the platinum ions within the carbon matrix, which may gain fundamentally new interest in functional patterning of hierarchical carbon nanostructures.
College: Faculty of Science and Engineering
Issue: 6
Start Page: 1578
End Page: 1586